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Synthesis of an acyltrifluoroborate and its fusion with azides to form amides
A uniquely stable acyl potassium trifluoroborate, potassium (2-phenylacetyl)trifluoroborate, has been synthesized and isolated. In the presence of an activating Lewis acid, this reagent reacts with asides to form amides in good yields.
Author(s): Molander, GA (Molander, Gary A.); Raushel, J (Raushel, Jessica); Ellis, NM (Ellis, Noel M.)
Source: JOURNAL OF ORGANIC CHEMISTRY, 75 (12): 4304-4306 JUN 18 2010
Language: English
Document Type: Article
KeyWords Plus: CROSS-COUPLING REACTIONS; ESTERS
Addresses: [Molander, Gary A.; Raushel, Jessica; Ellis, Noel M.] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA
Reprint Address: Molander, GA, Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA.
Funding Agency: Qatar National Research Fund - NIH - Merck Research Laboratories
Publisher: AMER CHEMICAL SOC
Publisher Address: 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
ISSN: 0022-3263
29-char Source Abbrev.: J ORG CHEM
ISO Source Abbrev.: J. Org. Chem.
Subject Category: Chemistry, Organic
ISI Document Delivery No.: 608CW
Author(s): Molander, GA (Molander, Gary A.); Raushel, J (Raushel, Jessica); Ellis, NM (Ellis, Noel M.)
Source: JOURNAL OF ORGANIC CHEMISTRY, 75 (12): 4304-4306 JUN 18 2010
Language: English
Document Type: Article
KeyWords Plus: CROSS-COUPLING REACTIONS; ESTERS
Addresses: [Molander, Gary A.; Raushel, Jessica; Ellis, Noel M.] Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA
Reprint Address: Molander, GA, Univ Penn, Dept Chem, Roy & Diana Vagelos Labs, Philadelphia, PA 19104 USA.
Funding Agency: Qatar National Research Fund - NIH - Merck Research Laboratories
Publisher: AMER CHEMICAL SOC
Publisher Address: 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
ISSN: 0022-3263
29-char Source Abbrev.: J ORG CHEM
ISO Source Abbrev.: J. Org. Chem.
Subject Category: Chemistry, Organic
ISI Document Delivery No.: 608CW
